物理化学中相是什么

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物理化学中相是什么求高手给解答

最佳答案

推荐答案

-具有均匀的物理和化学性质的均质部分是一个相。

-相可以是混合物(如糖水混合物),也可以是纯净物(如固态糖)。-相都是均匀的,题中所述的均相应该是指系统:有的系统是均相系统,有的是非均相系统。而非均相系统是由几个均相系统组成的(如冰水=冰+水)。(参考英文原文如下,欢迎指出不正之处)A phase may be defined as a homogeneous portion of a system that has uniform physical and chemical characteristics. Every pure material is considered to be a phase; so also is every solid, liquid, and gaseous solution. For example, the sugar–water syrup solution just discussed is one phase, and solid sugar is another. Each has different physical properties (one is a liquid, the other is a solid); furthermore, each is different chemically (i.e., has a different chemical composition); one is virtually pure sugar, the other is a solution ofH2O and C12H22O11. If more than one phase is present in a given system, each will have its own distinct properties, and a boundary separating the phases will exist, across which there will be a discontinuous and abrupt change in physical and/or chemical haracteristics.When two phases are present in a system, it is not necessary that there be a difference in both physical and chemical properties; a disparity in one or the other set of properties is sufficient. When water and ice are present in a container, two separate phases exist; they are physically dissimilar (one is a solid, the other is a liquid) but identical in chemical makeup. Also, when a substance can exist in two or more polymorphic forms (e.g., having both FCC and BCC structures), each of these structures is a separate phase because theirrespective physical characteristics differ.Sometimes, a single-phase system is termed homogeneous. Systems composed of two or more phases are termed mixtures or heterogeneous systems. Most metallic alloys and, for that matter, ceramic, polymeric, and composite systems are heterogeneous. Typically, the phases interact in such a way that the property combination of the multiphase system is different from, and more desirable than, either of the individual phases.(引用自MATERIALS SCIENCE and ENGINEERING an introduction by William D. Callister, Jr. & David G. Rethwisch, Page 300)

其他答案

物理化学中相(phase)指的是体系内部物理和化学性质完全均匀的部分称为相。相与相之间在指定条件下有明显的界面,在界面上宏观性质的改变是飞跃式的。体系中相的总数称为相数,用P表示。相关概念:

1、相律,是研究相平衡的基本规律,表示平衡物系中的自由度数,相数及独立组分数之间的关系。

(1)相与相之间有界面,各相可以用物理或机械方法加以分离,越过界面时性质会发生突变。

(2)一个相可以是均匀的,但不一定只含一种物质。体系的相数P∶气体:一般是一个相,如空气组分复杂。液体:视其混溶程度而定,可有1、2、3…个相。固体:有几种物质就有几个相,如水泥生料。但如果是固溶体时为一个相。固溶体:固态合金中,在一种元素的晶格结构中包含有其它元素的合金相称为固溶体。在固溶体晶格上各组分的化学质点随机分布均匀,其物理性质和化学性质符合相均匀性的要求,因而几个物质间形成的固溶体是一个相。

2、相平衡体系∶在宏观上没有任何物质从一相转移到另一相的体系。

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